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Question: A mixture of 1-iodoethane and 1-iodopropane is treated with sodium metal and dry ether to carry out ...

A mixture of 1-iodoethane and 1-iodopropane is treated with sodium metal and dry ether to carry out Wurtz reaction. Which of the following hydrocarbons will be formed?

A

Propane + Hexane

B

Ethane + Propane

C

Butane + Propane

D

Butane + Pentane + Hexane

Answer

Butane + Propane

Explanation

Solution

: CH3CH2I+2Na+ICH2CH2CH3EtherCH_{3}CH_{2}I + 2Na + ICH_{2}CH_{2}CH_{3}\overset{\quad Ether\quad}{\rightarrow}

CH3CHButanc CH2CH3+CH3CH2CH2 Pentanc CH3\mathrm { CH } _ { 3 } \mathrm { CH } _ { \text {Butanc } } ^ { \mathrm { CH } _ { 2 } } \mathrm { CH } _ { 3 } + \mathrm { CH } _ { 3 } \underset { \text { Pentanc } } { \mathrm { CH } _ { 2 } \mathrm { CH } _ { 2 } } \mathrm { CH } _ { 3 }

+CH3CH2CH2CH2hexaneCH2CH3+ CH_{3}CH_{2}\underset{hexane}{CH_{2}CH_{2}}CH_{2}CH_{3}