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Question: A metallic carbide on treatment with water gives a colourless gas which burns readily in air and whi...

A metallic carbide on treatment with water gives a colourless gas which burns readily in air and which gives a precipitate with ammoniacal silver nitrate solution. Gas evolved is.

A

Methane

B

Ethane

C

Acetylene

D

Ethylen

Answer

Acetylene

Explanation

Solution

CaC2+2H2OCa(OH)2+C2H2CaC_{2} + 2H_{2}O \rightarrow Ca(OH)_{2} + C_{2}H_{2}

CHCH+2[Ag(NH3)2]OHAgCCWhiteppt.Ag+4NH3+2H2OCH \equiv CH + 2\lbrack Ag(NH_{3})_{2}\rbrack OH \rightarrow Ag\underset{\text{Whiteppt.}}{- C \equiv C -}Ag + 4NH_{3} + 2H_{2}O