Question
Question: A metal crystallizes with a face centered cubic lattice. The edge length of the unit cell is \(408pm...
A metal crystallizes with a face centered cubic lattice. The edge length of the unit cell is 408pm. The diameter of the metal atom is:
A.288pm
B.176pm
C.200pm
D.None of the above
Solution
This question gives the knowledge about the FCC crystal lattice. Fcc crystal lattice is called as face-centered cubic crystal lattice. It contains six atoms at each face of the cube and eight atoms at the corners of the cube.
Formula used:
The formula used to determine the radius of the metal atom is as follows:
r=22a
Where r is the radius of the metal atom and a is the edge length of the unit cell.
Complete step by step answer:
Fcc crystal lattice contains six atoms at each face of the cube and eight atoms at the corners of the cube. The effective number of atoms in a FCC crystal unit cell is always 4. The coordination number of FCC lattice is 12. The elements which possess face centered unit cells are copper, aluminum, silver and so forth. Face centered crystal lattice is a closed packed structure.
Now, we will determine the radius of the metal atom is as follows:
⇒r=22a
Substitute the value of the edge length of the unit cell as 408pm in the above formula to determine the radius.
⇒r=22408
On simplifying, we get
⇒r=144pm
As we know, the diameter is the double of radius of the metal atom. So, the radius is multiplied by 2 to determine the diameter.
Therefore, the diameter of the metal atom is 288pm.
Hence, option A is the correct option.
Note:
Always remember that the effective number of atoms in a face centered cubic crystal unit cell is always 4. FCC crystal lattice contains six atoms at each face of the cube and eight atoms at the corners of the cube.