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Question

Chemistry Question on The solid state

A metal crystallises in a face centred cubic structure. If the edge length of its unit cell is a'a', the closest approach between two atoms in metallic crystal will be :

A

2a\sqrt{2} a

B

a2\frac{a}{\sqrt{2}}

C

2a2a

D

22a2\sqrt{2} a

Answer

a2\frac{a}{\sqrt{2}}

Explanation

Solution

In FCC, one of the face is like

By ΔABC\Delta ABC,

2a2=16r22a^{2} = 16r^{2}
r2=18a2\Rightarrow r^{2} = \frac{1}{8} a^{2}
r=122a\Rightarrow r = \frac{1}{2 \sqrt{2}} a

Distance of closest approach =2r=a2 = 2r = \frac{a}{\sqrt{2}}