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Question: A mass of an ideal gas of volume V at pressure P undergoes the cycle of changes shown in the graph –...

A mass of an ideal gas of volume V at pressure P undergoes the cycle of changes shown in the graph –

At which point is the gas coolest and hottest ?

Coolest hottest

A

X Y

B

Y X

C

Y Z

D

Z Y

Answer

Y Z

Explanation

Solution

For a mole of an ideal gas, the equation of state is PV = RT

or T = PVR\frac{PV}{R}

which is proportional to the product pV

At x , PV = (4 × 105) (1 × 10–4) = 40 Nm

At y, pV = (1 × 105) (5 × 10–4) = 50 Nm

At z, pV = (1 × 105) (1 × 10–4) = 10 Nm

Thus, T is maximum at y since pV is the highest and T is minimum at z since pV is the smallest

PV = RT