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Question

Physics Question on thermal properties of matter

A mass of 50g50\,g of water in a closed vessel, with surroundings at a constant temperature takes 22 minutes to cool from 30C30^\circ C to 25C25^\circ C. A mass of 100g100\,g of another liquid in an identical vessel with identical surroundings takes the same time to cool from 30C30^\circ C to 25C25^\circ C. The specific heat of the liquid is: (The water equivalent of the vessel is 30g30\,g.)

A

2.0 kcal/kg

B

7 kcal/kg

C

3 kcal/kg

D

0.5 kcal/kg

Answer

0.5 kcal/kg

Explanation

Solution

As the surrounding is identical, vessel is identical time taken to cool both water and liquid (from 30?C30?C to 25?C25?C is same 22 minutes, therefore
(dQdt)water=(dQdt)liquid\left(\frac{d Q}{d t}\right)_{water} =\left(\frac{d Q}{d t}\right)_{liquid}
or,(mwCw+W)ΔTt=(mC+W)ΔTtor, \, \frac{\left(m_{w} C_{w}+W\right)\Delta T}{t}=\frac{\left(m_{\ell}C_{\ell}+W\right)\Delta T}{t}
(W = water equivalent of the vessel)
or,mwCw=mCor, \, m_{w} C_{w} =m_{\ell} C_{\ell}
\therefore Specific heat of liquid, C=mwCwmC_{\ell} =\frac{m _{w} C_{w}}{m_{\ell}}
=50×1100=0.5kcalkg=\frac{50\times1}{100}=0.5 \, kcal \, kg