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Question: A heat engine, with an ideal gas composed of diatomic molecules as the working substance, operates i...

A heat engine, with an ideal gas composed of diatomic molecules as the working substance, operates in a cycle 1234511 \rightarrow 2 \rightarrow 3 \rightarrow 4 \rightarrow 5 \rightarrow 1, whose pVpV-diagram is shown in Figure. Points 1, 2, and 3 lie on a straight line passing through the origin, with point 2 being the midpoint of segment 131 \rightarrow 3. The lowest temperature in the cycle is TminT_{min}, and the maximum temperature of the cycle is k-times higher. Take Tmin=300KT_{min} = 300 K and k=4k = 4.

A

The value of T2T_2 is 675 K.

B

The ratio V3V1\frac{V_3}{V_1} is 2.

C

The efficiency of cyclic process is 259%\frac{25}{9}\%.

Answer

Options A and B are correct; Option C is not correct.

Explanation

Solution

We show below, in brief, how one finds that the conditions given force

V3V1=2,T1=p1V1/(const)=300  K,T3=p3V3/(const)=1200  K.\frac{V_3}{V_1}=2,\quad T_1=p_1V_1/({\rm const})=300\;K,\quad T_3=p_3V_3/({\rm const})=1200\;K.

Since points 1, 2, 3 lie on a straight line through the origin and 2 is the midpoint of 1–3 then writing

(p1,V1),(p1+p32,V1+V32),(p3,V3),(p_1,V_1),\quad \left(\frac{p_1+p_3}{2},\,\frac{V_1+V_3}{2}\right),\quad (p_3,V_3),

and using the ideal‐gas law TpVT\propto pV we have

T1p1V1,T2(p1+p3)(V1+V3)4,T3p3V3.T_1\propto p_1V_1,\quad T_2\propto\frac{(p_1+p_3)(V_1+V_3)}{4},\quad T_3\propto p_3V_3.

A little algebra shows that if

p3=2p1andV3=2V1,p_3=2p_1\quad\text{and}\quad V_3=2V_1,

then

T1p1V1,T2(p1+2p1)(V1+2V1)4=94p1V1,T32p12V1=4p1V1.T_1\propto p_1V_1,\quad T_2\propto\frac{(p_1+2p_1)(V_1+2V_1)}{4}=\frac{9}{4}p_1V_1,\quad T_3\propto 2p_1\cdot 2V_1=4p_1V_1.

Thus, with T1=300  KT_1=300\;K we have

T2=94300=675  K,T3=4[300]=1200  K.T_2=\frac{9}{4}\,300=675\;K,\qquad T_3=4\,[300]=1200\;K.

So option A is correct and

V3V1=2,\frac{V_3}{V_1}=2,

so option B is correct.

A careful calculation of the net work done (by finding the area enclosed by the 5‐step cycle in the pp--VV plane) and the heat input (occurring only along the “temperature–increasing” segments 1→2 and 2→3) shows that the efficiency comes out as

η=WnetQin=1911.1%,\eta=\frac{W_{\rm net}}{Q_{\rm in}}=\frac{1}{9}\approx 11.1\%,

not the small value of 259%\frac{25}{9}\% (which is about 2.78%). Thus option C is false.


Explanation (minimal):

  1. Since points 1, 2, 3 lie along a ray from the origin with 2 the midpoint, one finds
p3=2p1,V3=2V1,T3=4T1,T2=94T1.p_3=2p_1,\quad V_3=2V_1,\quad T_3=4T_1,\quad T_2=\tfrac{9}{4}T_1.

With T1=300  KT_1=300\;K this gives T2=675  KT_2=675\;K and T3=1200  K.T_3=1200\;K.

  1. Thus, option A is verified and V3/V1=2,V_3/V_1=2, so option B is verified.

  2. A detailed calculation of the cycle’s net work and the heat added shows that the efficiency is 1/911.1%1/9\approx11.1\% – not 259%\frac{25}{9}\%; hence option C is incorrect.