Question
Question: A graph between log t<sub>1/2</sub>and log a (abscissa) 'a' being the initial conc. of A in the reac...
A graph between log t1/2and log a (abscissa) 'a' being the initial conc. of A in the reaction.
A ®product, the rate law is –
A
–dtd[A] = k[A]0
B
–dtd[A] = k[A]
C
–dtd[A] = k[A]2
D
None of these
Answer
–dtd[A] = kA2
Explanation
Solution
t1/2 = k a(1–n)
log t1/2 = log k + (1 – n) log a
\ 1 – n = 1
n = 2
\ second order reaction