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Question: A graph between log t<sub>1/2</sub>and log a (abscissa) 'a' being the initial conc. of A in the reac...

A graph between log t1/2and log a (abscissa) 'a' being the initial conc. of A in the reaction.

A ®product, the rate law is –

A

d[A]dt\frac{d\lbrack A\rbrack}{dt} = k[A]0

B

d[A]dt\frac{d\lbrack A\rbrack}{dt} = k[A]

C

d[A]dt\frac{d\lbrack A\rbrack}{dt} = k[A]2

D

None of these

Answer

d[A]dt\frac{d\lbrack A\rbrack}{dt} = kAA2

Explanation

Solution

t1/2 = k a(1–n)

log t1/2 = log k + (1 – n) log a

\ 1 – n = 1

n = 2

\ second order reaction