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Question

Chemistry Question on p -Block Elements

A gas (X)(X) is obtained when copper reacts with dilute HNO3HNO_3. The gas thus formed reacts with oxygen to give brown fumes of (Y)(Y). (Y)(Y) when dissolved in water gives an important acid (Z)(Z) and the gas (X)(X). XX , YY and ZZ respectively are

A

NO;NO2;HNO3NO ; NO_2; HNO_3

B

NO2;NO;HNO3NO_2 ; NO ; HNO_3

C

N2O;NO;HNO2N_2O ; NO ; HNO_2

D

NO;N2O;HNO3NO ; N_2O ; HNO_3

Answer

NO;NO2;HNO3NO ; NO_2; HNO_3

Explanation

Solution

3Cu+8HNO3(dil)3Cu(NO3)2 {3Cu + 8HNO3_{(dil)} \to 3Cu(NO3)_2} +2NO(X)+4H2O+\,\underset{\text{(X)}}{ {2NO}}\,+ {4H2O} 2NO+O2<=> {2NO +O2 <=>} 2NO2(Y)\underset{\text{(Y)}}{ {2NO2}} 3NO2(Y)+H2O\underset{\text{(Y)}}{ {3NO2}}+ {H2O} \to 2HNO3(Z)+\underset{\text{(Z)}}{ {2HNO3}}+ NO(X)\underset{\text{(X)}}{ {NO}}