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Question: A gas mixture consists of 2 mole of oxygen and 4 mole of argon at temperature T. Neglecting all vibr...

A gas mixture consists of 2 mole of oxygen and 4 mole of argon at temperature T. Neglecting all vibrational modes, the total internal energy of the system is

A

4 RT

B

15 RT

C

9 RT

D

11 RT

Answer

11 RT

Explanation

Solution

Total internal energy of system

=Uoxygen+Uargon=μ1f12RT+μ2f22RT= U_{\text{oxygen}} + U_{\text{argon}} = \mu_{1}\frac{f_{1}}{2}RT + \mu_{2}\frac{f_{2}}{2}RT

=252RT+432RT=5RT+6RT=11RT= 2\frac{5}{2}RT + 4\frac{3}{2}RT = 5RT + 6RT = 11RT

[As f1 = 5 (for oxygen) and f2 = 3 (for argon)]