Question
Question: A gas is heated at a constant pressure. The fraction of heat supplied used for external work is: (...
A gas is heated at a constant pressure. The fraction of heat supplied used for external work is:
(A) γ1
(B) 1−γ1
(C) γ−1
(D) 1−γ21
Solution
Such a system must obey the first law of thermodynamics. Use the equation of the first law of thermodynamics to find the work done by the system.
Formula used: In this solution we will be using the following formulae;
ΔU=ΔQ−W where ΔU is the change in internal energy of the system, ΔQ is the change in thermal energy of (or the heat absorbed by) the system, and W is the work done by the system.
ΔQ=mcpΔT where mis the mass of the gas, cpis the specific heat at constant pressure, and ΔT is the change in temperature of the system.
ΔU=mcvΔT where cv is the specific capacity at constant volume.
Complete Step-by-Step Solution:
When the gas is heated, the change in thermal energy would be given by
ΔQ=mcpΔTwhere m is the mass of the gas, cp is the specific heat at constant pressure, and ΔT is the change in temperature of the system.
At the same time, the change in internal energy is given by
ΔU=mcvΔT where cv is the specific capacity at constant volume.
Now, from the first law of thermodynamics given as
ΔU=ΔQ−W where W is the work done by the system, we can find the work done as
W=ΔQ−ΔU
ΔQW=ΔQΔQ−ΔU=1−ΔQΔU
Replacing the known expressions into above equation, we have
ΔQW=1−mcpΔTmcvΔT=1−cpcv
The ratio cvcp is usually given the constant γ
Hence,
ΔQW=1−γ1
Thus, the correct option is B
Note: To avoid confusions, the thermodynamic equation can be written as
ΔU=ΔQ+W
However, in this format, the definition of W is the work done on (not by) the system. Hence, it is negative in value when work is done by the system