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Question: A gas is heated at a constant pressure. The fraction of heat supplied used for external work is: (...

A gas is heated at a constant pressure. The fraction of heat supplied used for external work is:
(A) 1γ\dfrac{1}{\gamma }
(B) 11γ1 - \dfrac{1}{\gamma }
(C) γ1\gamma - 1
(D) 11γ21 - \dfrac{1}{{{\gamma ^2}}}

Explanation

Solution

Such a system must obey the first law of thermodynamics. Use the equation of the first law of thermodynamics to find the work done by the system.
Formula used: In this solution we will be using the following formulae;
ΔU=ΔQW\Delta U = \Delta Q - W where ΔU\Delta U is the change in internal energy of the system, ΔQ\Delta Q is the change in thermal energy of (or the heat absorbed by) the system, and WW is the work done by the system.
ΔQ=mcpΔT\Delta Q = m{c_p}\Delta T where mmis the mass of the gas, cp{c_p}is the specific heat at constant pressure, and ΔT\Delta T is the change in temperature of the system.
ΔU=mcvΔT\Delta U = m{c_v}\Delta T where cv{c_v} is the specific capacity at constant volume.

Complete Step-by-Step Solution:
When the gas is heated, the change in thermal energy would be given by
ΔQ=mcpΔT\Delta Q = m{c_p}\Delta Twhere mm is the mass of the gas, cp{c_p} is the specific heat at constant pressure, and ΔT\Delta T is the change in temperature of the system.
At the same time, the change in internal energy is given by
ΔU=mcvΔT\Delta U = m{c_v}\Delta T where cv{c_v} is the specific capacity at constant volume.
Now, from the first law of thermodynamics given as
ΔU=ΔQW\Delta U = \Delta Q - W where WW is the work done by the system, we can find the work done as
W=ΔQΔUW = \Delta Q - \Delta U
WΔQ=ΔQΔUΔQ=1ΔUΔQ\dfrac{W}{{\Delta Q}} = \dfrac{{\Delta Q - \Delta U}}{{\Delta Q}} = 1 - \dfrac{{\Delta U}}{{\Delta Q}}
Replacing the known expressions into above equation, we have
WΔQ=1mcvΔTmcpΔT=1cvcp\dfrac{W}{{\Delta Q}} = 1 - \dfrac{{m{c_v}\Delta T}}{{m{c_p}\Delta T}} = 1 - \dfrac{{{c_v}}}{{{c_p}}}
The ratio cpcv\dfrac{{{c_p}}}{{{c_v}}} is usually given the constant γ\gamma
Hence,
WΔQ=11γ\dfrac{W}{{\Delta Q}} = 1 - \dfrac{1}{\gamma }

Thus, the correct option is B

Note: To avoid confusions, the thermodynamic equation can be written as
ΔU=ΔQ+W\Delta U = \Delta Q + W
However, in this format, the definition of WW is the work done on (not by) the system. Hence, it is negative in value when work is done by the system