Question
Chemistry Question on Thermodynamics
A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5atm from an initial volume of 2.50L to a final volume of 4.50L. The change in internal energy ΔU of the gas in joules will be
A
-500J
B
-505J
C
#ERROR!
D
1136.25J
Answer
-505J
Explanation
Solution
ΔU=q+w
For adiabatic process, q=0
∴ΔU=w
=−P⋅ΔV
=−2.5atm×(4.5−2.5)L
=−2.5×2L−atm
=−5×101.3J
=−506.5J
≈−505J