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Question

Chemistry Question on The solid state

A forms hcphcp lattice and B are occupying 1/3rd1/3^{rd} of tetrahedral voids, then the formula of compound is

A

ABAB

B

A3B2A_3B_2

C

A2B3A_2B_3

D

AB4AB_4

Answer

A3B2A_3B_2

Explanation

Solution

Let no. of atoms of A used in close packing = n Number of tetrahedral voids = 2n Number of atoms of B=13×2n=23nB=\frac{1}{3}\times2n=\frac{2}{3}n A:B=n:23n=3:2A : B=n : \frac{2}{3}n=3 : 2 Formula of the compound =A3B2 A_{3}B_{2}