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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

A cyclic hydrocarbon molecule has all the carbon and hydrogen is a single plane. All the carbon-carbon bonds are of same length, less than 1.54??butmorethan1.54\,?? but more than 1.34 ,?? $ The C-C bond angle will be:

A

109o28{{109}^{o}}28

B

100o{{100}^{o}}

C

180o{{180}^{o}}

D

120o{{120}^{o}}

Answer

120o{{120}^{o}}

Explanation

Solution

Cyclic hydrocarbon, with carbon-carbon bond length between 1.34??and1.34\, ?? and 1.54,?? is benzene in which due to resonance, C-C, bond length is 1.39??1.39\, ?? (i. e., between 1.34??1.54??).Benzeneisahexagonalmoleculewithbondangleequalto1.34\,??1.54\,?? ). Benzene is a hexagonal molecule with bond-angle equal to {{120}^{o}}. $