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Question: A container of \[5l\] has a gas pressure of \[0.8m\]column of Hg. This is joined to an evacuated con...

A container of 5l5l has a gas pressure of 0.8m0.8mcolumn of Hg. This is joined to an evacuated container of 3l3lcapacity. The resulting pressure will be: (at constant temperatureTT)

& A.\dfrac{4}{3}m \\\ & B.0.5m \\\ & C.2.0m \\\ & D.\dfrac{3}{4}m \\\ \end{aligned}$$
Explanation

Solution

Ideal gas law or the general gas equation is the combination of Boyle’s Law, Charles’s law, Avogadro’s law and Gay Lussac’s law. It gives the relationship between the pressure PP applied on a VV volume of the gas which contains nn number of molecules at temperature TT.

Formula used:
PV=nRTPV=nRT

Complete step-by-step answer:
Let us assume that the gas in the container is ideal and contains nn number of molecules. Here since the temperature is constant, we can say that the system is undergoing an isothermal process.
Given that the initially the pressure in the gas is P1=0.8mP_{1}=0.8m and the volume is V1=5lV_{1}=5l and since the container of capacity 5l5l is connected to another whose maximum capacity is3l3l , then we can say that the new volume V2=3+5=8lV_{2}=3+5=8l, let the P2P_{2} be the final pressure .
Then, from ideal gas law we now that PV=nRTPV=nRT
Clearly, nn, RR, TT are constant here.
Then, we get PV=constantPV=constant
    P1V1=P2V2\implies P_{1}V_{1}=P_{2}V_{2}
Substituting the values we get 0.8×5=P2×80.8\times 5=P_{2}\times 8
    P2=0.8×58=0.5m\implies P_{2}=\dfrac{ 0.8\times 5}{8}=0.5m
Hence the answer is option B.0.5mB.0.5m

So, the correct answer is “Option B”.

Additional Information: However, the ideal gas law doesn’t give any information of the nature of reaction, i.e. when the gas is expanding or compressing does it absorb heat or release heat. Also as the name suggests these gases are ideal and such gases don't exist in the real world they are hypothetical in nature.

Note: From ideal gas law, we know that PV=nRTPV=nRT where PP is the pressure applied on the and VV is the volume of the gas which contains nn number of molecules at temperature TT and RR is the gas constant. We can vary the different parameters to understand the behaviours of the gas in various conditions.