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Question

Chemistry Question on Hydrocarbons

A compound is treated with NaNH2NaNH_2 to give sodium salt. Identify the compound.

A

C2H2C_2 H_2

B

C6H6C_6 H_6

C

C2H6C_2 H_6

D

C2H4C_2 H_4

Answer

C2H2C_2 H_2

Explanation

Solution

Sodamide is strong base, attract the more acidic hydrogen and gives sodium salt
HCCH+NaNH2HCCNa+H-C \equiv C -H + NaNH_2 \longrightarrow H-C\equiv C^- Na^+
\hspace60mm _{}^{Sodium\, ethynide}
\hspace80mm +\frac{1}{2}H_2