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Question

Chemistry Question on The solid state

A compound is formed by two elements A and B. The element B forms cubic close packed structure and atoms of A occupy 13\frac 13 of tetrahedral voids. If the formula of the compound is A,By. then the value of x +y is in option

A

4

B

3

C

2

D

5

Answer

5

Explanation

Solution

Number of tetrahedral voids = 2 x Number of atoms of B
Number of atoms of A = 13\frac 13 x Number of tetrahedral voids
Let the number of atoms of B be "x" and the number of atoms of A be "y."
From the given information, we have the equations:
x = Number of atoms of B
y = 13\frac 13 * 2x = 2x3\frac {2x}{3}
Since the formula of the compound is AB, the total number of atoms in the compound is x + y.
Total number of atoms = x + y = x + 2x3\frac {2x}{3} = 2x3\frac {2x}{3}
So, the value of x + y is 5x3\frac {5x}{3}.
Since we are looking for the value of x + y in terms of a constant value, we can simplify the fraction by choosing a suitable value for x. Let's choose x = 3 (which is a common choice in these types of problems):
x = 3y = 2x3\frac {2x}{3} = 2
So, x + y = 3 + 2 = 5.

Therefore, the correct option is (D): 5