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Question

Chemistry Question on Group 17 Elements

A certain compound X when treated with copper sulphate solution yields a brown precipitate. On adding hypo solution, the precipitate turns white. The compoundXis

A

K2CO3K_2CO_3

B

KI

C

KBr

D

K3PO4K_3PO_4

Answer

KI

Explanation

Solution

When potassium iodide is reacted with CuS04,
it gives iodine gas which is brown colour. This
iodine react with sodium thiosulphate and form
white precipitate of sodium tetrathionate.
2CuSO4+4KIK2SO4+I2+2CuI2CuSO_4 \, + \, 4 KI \, \longrightarrow \, K_2 SO_4 \, + \, I_2 \, + 2CuI
2Na2S2O3+I2Na2S4O6+2NaI2Na_2S_2O_3 \, + \, I_2 \, \longrightarrow \, Na_2S_4O_6 \, + \, 2NaI