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Question

Chemistry Question on GROUP 1 ELEMENTS

A certain compound XX imparts a golden yellow flame. When zinc powder is heated with concentrated solution of XX, H2H_2 gas is evolved. XX combines with CO2CO_2 to give a salt YY. YY is a hydrated salt which on reaction with HClHCl or excess of CO2CO_2 gives another salt ZZ which is an important part of baking powder. Identify XX, YY and ZZ.

A

a

B

b

C

c

D

d

Answer

a

Explanation

Solution

Zn+ {Zn +} 2NaOH(X)\underset{\text{(X)}}{ {2NaOH}} Na2ZnO2+H2 { \to Na2ZnO2 +H2} 2NaOH(X)\underset{\text{(X)}}{ {2NaOH}} +CO2\,+ \, {CO2 \to} Na2CO3(Y)+H2O\underset{\text{(Y)}}{ {Na2CO3}} {\,+ H2O} Na2CO3+(Y)HCl\underset{\text{(Y)}}{ {Na2CO3}\,+} {HCl \to} NaHCO3(Z)+NaCl\underset{\text{(Z)}}{ {NaHCO3}}\,+ {NaCl} Na2CO3(Y)+CO2+H2O\underset{\text{(Y)}}{ {Na2CO3}}+\, {CO2 +H2O \to} 2NaHCO3(Z)\underset{\text{(Z)}}{ {2NaHCO3}}