Solveeit Logo

Question

Question: A CCP of n spheres of radius r, n spheres of radius 0.414 r and 2n spheres of radius 0.225 r are int...

A CCP of n spheres of radius r, n spheres of radius 0.414 r and 2n spheres of radius 0.225 r are introduced in the octahedral and tetrahedral void respectively. Therefore packing fraction of the lattice.

A

0.74

B

0.81

C

0.68

D

0.79

Answer

0.81

Explanation

Solution

P.F =

4×43πr3+4×43π×(0.414r)3+8×43π×(0.225r)3(22r)3\frac{4 \times \frac{4}{3}\pi r^{3} + 4 \times \frac{4}{3}\pi \times (0.414r)^{3} + 8 \times \frac{4}{3}\pi \times (0.225r)^{3}}{(2\sqrt{2}r)^{3}}

P.F = 4×43πr3[1+(0.414)3+2×(0.225)3]162r3\frac{4 \times \frac{4}{3}\pi r^{3}\lbrack 1 + (0.414)^{3} + 2 \times (0.225)^{3}\rbrack}{16\sqrt{2}r^{3}}

P.F = π32[1+(0.414)3+2×(0.225)3\frac{\pi}{3\sqrt{2}}\lbrack 1 + (0.414)^{3} + 2 \times (0.225)^{3}

= π32\frac{\pi}{3\sqrt{2}} (1 + 0.070958 + 0.022781)

or P.F = 0.8096 ~ 0.81