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Question: A calorimeter of mass \(50g\) and specific heat capacity \(0.42\,J\,{g^{ - 1o}}{C^{ - 1}}\) contains...

A calorimeter of mass 50g50g and specific heat capacity 0.42Jg1oC10.42\,J\,{g^{ - 1o}}{C^{ - 1}} contains some mass of water at 20oC{20^o}C. A metal piece of mass 20g20\,g at 100oC{100^o}C is dropped into the calorimeter. After stirring, the final temperature of the mixture is found to be 22oC{22^o}C. Find the mass of water used in the calorimeter.
[Specific heat capacity of the metal piece =0.3Jg1oC1 = 0.3\,J\,{g^{ - 1}}^o{C^{ - 1}}
Specific heat capacity of water=4.2Jg1oC1 = 4.2\,J\,{g^{ - 1}}^o{C^{ - 1}}]

Explanation

Solution

While solving the question we must to keep in mind the concept of calorimetry. The principle of calorimetry indicates the law of conservation energy, i.e. the total heat lost by the hot body is equal to the total heat gained by the cold body.

Complete step by step answer:
Heat energy given by metal piece
=m.c.ΔT1= m.c.\Delta {T_1}
=20×0.3×(10022)= 20 \times 0.3 \times (100 - 22)
=468J= 468\,J
Heat energy gained by water
mw×cw×ΔT2{m_w} \times {c_w} \times \Delta {T_2}
=mw×4.2×(2220)= {m_w} \times 4.2 \times (22 - 20)
=mw×8.4J= {m_w} \times 8.4\,J
Heat energy gained by calorimeter
=mC×cc×ΔT2= {m_C} \times {c_c} \times \Delta {T_2}
=50×0.42×(2220)= 50 \times 0.42 \times (22 - 20)
=42Joule.= 42\,Joule.
By principle of calorimeter
Heat load ==heat gained
Heat energy given by metal
==Heat energy gained
By water++Heat energy gained by calorimeter.
468=(mw×8.4)+42468 = \left( {{m_w} \times 8.4} \right) + 42
mw=50.7g{m_w} = 50.7\,g
Therefore mass ++water used in calorimeter is 50.7g50.7\,g

Note:
When two bodies of different temperatures (preferably a solid and a liquid) are placed in physical contact with each other, the heat is transferred from the body with higher temperature to the body with lower temperature until thermal equilibrium is attained between them.