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Question

Chemistry Question on Equilibrium

A buffer solution has equal volumes of 0.2MNH4OH0.2M \, NH_4OH and 0.02MNH4Cl0.02\, M \, NH_4 Cl. The pkbp^{kb} of the base is 55. The pHpH is

A

10

B

9

C

4

D

7

Answer

10

Explanation

Solution

pOH=pKb+log[salt][base]pOH = p K_{b}+\log \frac{[ salt ]}{[ base ]}

(Henderson's equation)

=5+log0.020.2=5+log110=5+\log \frac{0.02}{0.2}=5+\log \frac{1}{10}
=5+(1)=4=5+(-1)=4
pH=14pOH=144=10pH =14- pOH =14-4=10