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Question: A bottle of cold drink contains 200 mL liquid in which \(C{O_2}\) is 0.1 molar. Suppose \(C{O_2}\) b...

A bottle of cold drink contains 200 mL liquid in which CO2C{O_2} is 0.1 molar. Suppose CO2C{O_2} behaves like an ideal gas, the volume of the dissolved CO2C{O_2} at STP is:
A) 0.244L
B) 22.4L
C) 0.448L
D) 44.8L

Explanation

Solution

Multiply no. of moles of solute with 22.4 to get the volume of the dissolved CO2C{O_2} at STP. By using the formula of Molarity we can find the no. of moles of solute, as values of volume and molarity are given in question.

Formulas used:
Molarity = No.  of  moles  of  the  soluteVolume  of  the  solution  in  litres{\dfrac{ No.\; of\; moles\; of\; the\; solute}{Volume\; of\; the\; solution\; in \;litres}}
Volume of n moles of solute at STP= 22.4×\times No. of moles of solute

Complete answer:
It is given the question that there is bottle of cold drink such that
Volume of the solution (V) = 200mL
We have to convert volume of solution into liters which can be done by dividing volume by 1000,
Therefore, Volume of solution in liters is = 2001000\dfrac{{200}}{{1000}}= 0.2 L
Amount of CO2C{O_2} present in solution i.e. molarity of solution = 0.1 molar
As we know that formula of molarity, so by using formula of molarity that is,
Molarity = No.  of  moles  of  the  soluteVolume  of  the  solution  in  litres{\dfrac{ No.\; of\; moles\; of\; the\; solute}{Volume\; of\; the\; solution\; in \;litres}}
Therefore by putting the values in the formula we get,
No. of moles of solute that is CO2C{O_2} = 0.1×0.1 \times 2001000\dfrac{{200}}{{1000}} moles
Therefore, no. of moles of CO2C{O_2} = 0.02 moles
Now the volume of the CO2C{O_2} dissolved at STP as per formula will be,
Volume of n moles of solute at STP = 22.4×\times no. of moles of solute
By putting values in it we get,
Volume of CO2C{O_2} dissolved at STP = 22.4×\times0.02
Hence Volume of CO2C{O_2} dissolved at STP = 0.448 liters

So the correct option is (C).

Note: Always remember that while calculating molarity volume of the solution should be in liters and not in any other unit. In the above solution volume is in mL so first we have to do the conversion to litres then go for further calculations otherwise the answer will be wrong.