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Question: A block having \(12\;g\) of an element is placed in a room. This element is a radioactive element wi...

A block having 12  g12\;g of an element is placed in a room. This element is a radioactive element with a half-life of 15  15\; years. After how many years will there be just 1.5  g1.5\;g of the element in the box?
(A) 40  40\; years
(B) 45  45\; years
(C) 20  20\; years
(D) 15  15\; years

Explanation

Solution

The decay of a radioactive element is exponential, the half-life indicates the time taken by the element to reduce to half of its previous amount. We can first determine the decay constant by going through the definition of half-life and then put it in the formula for the exponential decay.
Formula used:
eλt=NN0{e^{ - \lambda t}} = \dfrac{N}{{{N_0}}}

Complete step by step answer:
It is given in the question that,
The initial mass of the element, N0=12  g{N_0} = 12\;g
The half-life of the element, t12=15  years{t_{\dfrac{1}{2}}} = 15\;years
We know that the half-life of an element is given by,
t12=ln2λ{t_{\dfrac{1}{2}}} = \dfrac{{\ln 2}}{\lambda }
where λ\lambda is the decay constant.
To find λ\lambda we rearrange the equation and keep the value of ln2\ln 2 as 0.693  0.693\;
Therefore,
λ=0.69315\lambda = \dfrac{{0.693}}{{15}}
λ=0.0462\Rightarrow \lambda = 0.0462
The exponential decay of an element is given by,
eλt=NN0{e^{ - \lambda t}} = \dfrac{N}{{{N_0}}}
where tt is the time elapsed,
NN is the amount of element that is left,
N0{N_0} is the initial amount of element,
λ\lambda is the decay constant.
It is given in the question that,
N=1.5gN = 1.5g
\Rightarrow N0=12g{N_0} = 12g
\Rightarrow λ=0.0462\lambda = 0.0462
Putting these values in the formula,
eλt=NN0{e^{ - \lambda t}} = \dfrac{N}{{{N_0}}}
e0.0462t=1.512\Rightarrow {e^{ - 0.0462t}} = \dfrac{{1.5}}{{12}}
Taking logarithm on both sides,
\Rightarrow ln(e0.0462t)=ln(1.512)\ln ({e^{ - 0.0462t}}) = \ln \left( {\dfrac{{1.5}}{{12}}} \right)
Since,
lnxn=nlnx\ln {x^n} = n\ln x
The equation can be written as,
0.0462t=ln(0.125)- 0.0462t = \ln \left( {0.125} \right)
From the log table,
ln(0.125)=2.0794\ln (0.125) = - 2.0794
Using this value,
t=2.07940.0462t = \dfrac{{ - 2.0794}}{{ - 0.0462}}
\Rightarrow t=45t = 45

Therefore the time taken is equal to 45  45\; years, this makes option (B) the correct answer.

Note: An alternate solution can be that the half-life is a widely used term to define the stability of a radioactive substance. To avoid lengthy calculations, we can compare the number of half-lives of the element passed with the amount left. Like if we repeatedly divide 12  12\; by 22 we find that on the third time the amount becomes 1.5  1.5\; , this means that it takes three half-lives for the element to decay by this amount, and 3×t123 \times {t_{\dfrac{1}{2}}} is 45  45\; years. This method can be used in competitive exams with multiple-choice questions that do not require a full solution.