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Question

Chemistry Question on Chemical Kinetics

AA and BB are two substances undergoing radioactive decay in a container The half life of AA is 15min15 min and that of BB is 5min5\, min If the initial concentration of BB is 44 times that of AA and they both start decaying at the same time, how much time will it take for the concentration of both of them to be same? ______ min

Answer

The correct answer is 15.
[A]t​=[A]0​e−kt
For A : Let [A]t​ be y and [A]0​ be x;k=t1/2​ln2​=
15minln2​
y=xe−kt
=xe−(15ln2​)t
For B: [B]t​=[B]0​e−kt
Let [B]t​=y;[B]0​=4x;k=t1/2​ln2​=5minln2​
y=4xe−(5ln2​)t
⇒xe−(15ln2​)t=4xe−(5ln2​)t
et(5ln2​15ln2​)=4
t×[5ln2​−15ln2​]=ln4
t×ln2[51​−151​]=2ln2
t=15min