Question
Chemistry Question on Chemical Kinetics
A and B are two substances undergoing radioactive decay in a container The half life of A is 15min and that of B is 5min If the initial concentration of B is 4 times that of A and they both start decaying at the same time, how much time will it take for the concentration of both of them to be same? ______ min
Answer
The correct answer is 15.
[A]t=[A]0e−kt
For A : Let [A]t be y and [A]0 be x;k=t1/2ln2=
15minln2
y=xe−kt
=xe−(15ln2)t
For B: [B]t=[B]0e−kt
Let [B]t=y;[B]0=4x;k=t1/2ln2=5minln2
y=4xe−(5ln2)t
⇒xe−(15ln2)t=4xe−(5ln2)t
et(5ln215ln2)=4
t×[5ln2−15ln2]=ln4
t×ln2[51−151]=2ln2
t=15min