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Question: 9.2 grams of \(N _ { 2 } O _ { 4 ( g ) }\) is taken in a closed one litre vessel and heated till t...

9.2 grams of N2O4(g)N _ { 2 } O _ { 4 ( g ) } is taken in a closed one litre vessel and heated till the following equilibrium is reached

N2O4(g)N _ { 2 } O _ { 4 ( g ) }2NO2(g)2 N O _ { 2 ( g ) } . At equilibrium, 50% N2O4(g)N _ { 2 } O _ { 4 ( g ) } is dissociated. What is the equilibrium constant (in mol litre–1) (Molecular weight of N2O4=92)\left. N _ { 2 } O _ { 4 } = 92 \right)

A

0.1

B

0.4

C

0.2

D

2

Answer

0.2

Explanation

Solution

Kc=[NO2]2[N2O4]K _ { c } = \frac { \left[ N O _ { 2 } \right] ^ { 2 } } { \left[ N _ { 2 } O _ { 4 } \right] } =4×(0.05)20.05=4×0.05=0.2= \frac { 4 \times ( 0.05 ) ^ { 2 } } { 0.05 } = 4 \times 0.05 = 0.2