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Chemistry Question on Organic Chemistry

9.3 \, \text{g of aniline is subjected to reaction with excess of acetic anhydride to prepare acetanilide. The mass of acetanilide produced if the reaction is 100\% completed is } \\_\\_\\_\\_\\_ \times 10^{-1} \, \text{g.} \\\ \text{(Given molar mass in g mol}^{-1}\text{) N: 14, O: 16, C: 12, H: 1}

Answer

The reaction between aniline and acetic anhydride produces acetanilide. The balanced equation is:

C6H5NH2+CH3COOCOCH3C6H5NHCOCH3+CH3COOHC_6H_5NH_2 + CH_3COOCOCH_3 \rightarrow C_6H_5NHCOCH_3 + CH_3COOH

Given:
- Molar mass of aniline (C6H7NC_6H_7N) = 93g/mol93 \, \text{g/mol}
- Molar mass of acetanilide (C8H9NOC_8H_9NO) = 135g/mol135 \, \text{g/mol}

Calculate moles of aniline:
naniline=9.393=0.1molesn_{\text{aniline}} = \frac{9.3}{93} = 0.1 \, \text{moles}

Since the reaction is 1:11:1, moles of acetanilide produced = moles of aniline = 0.1moles0.1 \, \text{moles}.

Mass of acetanilide produced:
Mass=n×molar mass=0.1×135=13.5g\text{Mass} = n \times \text{molar mass} = 0.1 \times 135 = 13.5 \, \text{g}

Thus, 13.5g13.5 \, \text{g} or 135×101g135 \times 10^{-1} \, \text{g} of acetanilide is produced.
The Correct answer is: 135