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Question: If $a_0$ be the radius of first Bohr's orbit of H-atom, the de-Broglie's wavelength of an electron r...

If a0a_0 be the radius of first Bohr's orbit of H-atom, the de-Broglie's wavelength of an electron revolving in the second Bohr's orbit will be :

A

6πa06\pi a_0

B

4πa04\pi a_0

C

2πa02\pi a_0

D

None of these

Answer

4πa04\pi a_0

Explanation

Solution

The de Broglie wavelength (λ\lambda) of an electron in a Bohr orbit is related to the orbit's radius (rr) and the principal quantum number (nn) by Bohr's second postulate and de Broglie's hypothesis. Combining mvr=nh2πmvr = \frac{nh}{2\pi} and λ=hmv\lambda = \frac{h}{mv}, we get 2πr=nλ2\pi r = n\lambda. The radius of the nn-th Bohr orbit (rnr_n) is given by rn=n2r1r_n = n^2 r_1, where r1r_1 is the radius of the first Bohr orbit. In this problem, r1=a0r_1 = a_0. So, for the nn-th orbit, rn=n2a0r_n = n^2 a_0. We need to find the de Broglie wavelength for the second Bohr orbit, which means n=2n=2. The radius of the second Bohr orbit is r2=22a0=4a0r_2 = 2^2 a_0 = 4a_0. Using the relation 2πrn=nλn2\pi r_n = n\lambda_n, for n=2n=2: 2πr2=2λ22\pi r_2 = 2\lambda_2, which gives λ2=πr2\lambda_2 = \pi r_2. Substituting the value of r2r_2: λ2=π(4a0)=4πa0\lambda_2 = \pi (4a_0) = 4\pi a_0. Alternatively, we can use the derived formula λn=2πrn/n\lambda_n = 2\pi r_n / n. For n=2n=2 and r2=4a0r_2 = 4a_0, λ2=2π(4a0)/2=4πa0\lambda_2 = 2\pi (4a_0) / 2 = 4\pi a_0. Another way is to use the derived formula λn=2πrn/n\lambda_n = 2\pi r_n / n. Since rn=n2a0r_n = n^2 a_0, λn=2π(n2a0)/n=2πna0\lambda_n = 2\pi (n^2 a_0) / n = 2\pi n a_0. For n=2n=2, λ2=2π(2)a0=4πa0\lambda_2 = 2\pi (2) a_0 = 4\pi a_0.