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Question: Identify the product 'B' in the following reaction sequence. $C_2H_5-Br \xrightarrow[Dry ether]{Mg}...

Identify the product 'B' in the following reaction sequence.

C2H5BrDryetherMgACH3OHBC_2H_5-Br \xrightarrow[Dry ether]{Mg} A \xrightarrow{CH_3OH} B

A

H3CCH2CH3H_3C-CH_2-CH_3

B

C2H5OCH3C_2H_5-O-CH_3

C

C2H6C_2H_6

D

C2H5OHC_2H_5-OH

Answer

C2H6C_2H_6

Explanation

Solution

  1. Formation of Grignard Reagent:

    C2H5-Br+Mgdry etherC2H5MgBr(Product A)\text{C}_2\text{H}_5\text{-Br} + \text{Mg} \xrightarrow{\text{dry ether}} \text{C}_2\text{H}_5\text{MgBr} \quad \text{(Product A)}
  2. Reaction with Methanol:

    The Grignard reagent, being strongly basic, reacts with methanol (CH3OHCH_3OH) by abstracting a proton:

    C2H5MgBr+CH3OHC2H6+MgBrOCH3\text{C}_2\text{H}_5\text{MgBr} + \text{CH}_3\text{OH} \rightarrow \text{C}_2\text{H}_6 + \text{MgBrOCH}_3

    Thus, product B is ethane (C2H6C_2H_6).