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Question: The av. K.E./mole of an ideal monoatomic gas at 27°C is...

The av. K.E./mole of an ideal monoatomic gas at 27°C is

A

900 cal

B

1800 cal

C

300 cal

D

None

Answer

900 cal

Explanation

Solution

The temperature is converted to Kelvin: T=27C+273=300 KT = 27^\circ\text{C} + 273 = 300 \text{ K}. For an ideal monoatomic gas, the degrees of freedom f=3f=3. Using the equipartition theorem, the average kinetic energy per mole is KEmole=f2RT\text{KE}_{\text{mole}} = \frac{f}{2}RT. Using R2 cal/mol\cdotpKR \approx 2 \text{ cal/mol·K}, KEmole=32×(2 cal/mol\cdotpK)×(300 K)=900 cal/mol\text{KE}_{\text{mole}} = \frac{3}{2} \times (2 \text{ cal/mol·K}) \times (300 \text{ K}) = 900 \text{ cal/mol}.