Solveeit Logo

Question

Chemistry Question on Phosphorus

50cm350 \, cm^3 of 0.2NHCl0.2 \, N \, HCl is titrated against 0.1NNaOH0.1 \, N \, NaOH solution. The titration was discontinued after adding 50cm350\, cm^3 of NaOHNaOH. The remaining titration is completed by adding 0.5NKOH0.5 \, N \, KOH. The volume of KOHKOH required for completing the titration is

A

10cm310\, cm^3

B

12cm312 \,cm^3

C

16.2cm316.2 \, cm^3

D

21.0cm321.0\, cm^3

Answer

10cm310\, cm^3

Explanation

Solution

No. of equivalent of HClHCl remaining after adding 50cm350\, cm ^{3} of 0.1NNaOH=0.2×500.1×501000.1\, N\, NaOH =\frac{0.2 \times 50-0.1 \times 50}{100} =0.5100=\frac{0.5}{100} \therefore Volume of 0.5N0.5\, N KOH required 0.5100\frac{0.5}{100} eq V×0.51000\equiv \frac{V \times 0.5}{1000} V=0.5100×10000.5V =\frac{0.5}{100} \times \frac{1000}{0.5} =10cm3=10\, cm ^{3}