Question
Chemistry Question on Phosphorus
50cm3 of 0.2NHCl is titrated against 0.1NNaOH solution. The titration was discontinued after adding 50cm3 of NaOH. The remaining titration is completed by adding 0.5NKOH. The volume of KOH required for completing the titration is
A
10cm3
B
12cm3
C
16.2cm3
D
21.0cm3
Answer
10cm3
Explanation
Solution
No. of equivalent of HCl remaining after adding 50cm3 of 0.1NNaOH=1000.2×50−0.1×50 =1000.5 ∴ Volume of 0.5N KOH required 1000.5 eq ≡1000V×0.5 V=1000.5×0.51000 =10cm3