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Question: One mole of an ideal monoatomic gas is caused to go through the cycle shown in figure. Then the chan...

One mole of an ideal monoatomic gas is caused to go through the cycle shown in figure. Then the change the internal energy in expanding the gas from a to c along the path abc is :-

A

3P₀V₀

B

6RT₀

C

4.5RT₀

D

10.5RT₀

Answer

10.5RT₀

Explanation

Solution

The internal energy of an ideal gas depends only on its temperature. For one mole of a monoatomic ideal gas, the internal energy is given by U=32RTU = \frac{3}{2}RT. The change in internal energy is ΔU=32R(TfTi)\Delta U = \frac{3}{2}R(T_f - T_i).

From the P-V diagram, state 'a' has pressure P0P_0 and volume V0V_0. Assuming n=1n=1 mole, P0V0=RTaP_0V_0 = RT_a. Let Ta=T0T_a = T_0. So, P0V0=RT0P_0V_0 = RT_0.

State 'c' has pressure 2P02P_0 and volume 4V04V_0. The temperature at state 'c' is Tc=PcVcR=(2P0)(4V0)R=8P0V0RT_c = \frac{P_c V_c}{R} = \frac{(2P_0)(4V_0)}{R} = \frac{8P_0V_0}{R}. Substituting P0V0=RT0P_0V_0 = RT_0, we get Tc=8RT0R=8T0T_c = \frac{8RT_0}{R} = 8T_0.

The change in internal energy from 'a' to 'c' is ΔU=32R(TcTa)=32R(8T0T0)=32R(7T0)=10.5RT0\Delta U = \frac{3}{2}R(T_c - T_a) = \frac{3}{2}R(8T_0 - T_0) = \frac{3}{2}R(7T_0) = 10.5 RT_0. The path taken ('abc') does not affect the change in internal energy, as it is a state function.