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Question: Which of the following is correct representation of electronic configuration of valence shell of N-a...

Which of the following is correct representation of electronic configuration of valence shell of N-atom in its ground state:

A

1 1 1

B

レ レ レ

C

Both (1) and (2)

D

None of the above

Answer

Option (3)

Explanation

Solution

Nitrogen (N) has atomic number 7, so its ground state electronic configuration is 1s22s22p31s^2 2s^2 2p^3. The valence shell is the second shell, 2s22p32s^2 2p^3. The 2s2s orbital contains two electrons with opposite spins (Pauli's principle). The three 2p2p orbitals are degenerate and contain three electrons. According to Hund's rule, these three electrons occupy each 2p2p orbital singly with parallel spins. Both options (1) and (2) correctly represent this configuration, differing only in the arbitrary direction of spins (e.g., all up vs. all down for parallel spins, or \uparrow\downarrow vs \downarrow\uparrow for paired spins).