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Question

Chemistry Question on Equilibrium

40ml40\, ml of 0.1M0.1\, M ammonia solution is mixed with 20ml20 \,ml of 0.1MHCl0.1\, M\, HCl. What is the pHpH of the mixture? (pKb\left( p K_{b}\right. of ammonia solution is 4.74)\left.4.74\right)

A

4.74

B

2.26

C

9.26

D

5

Answer

9.26

Explanation

Solution

Handerson-Hasselbalch equation pOH=pKb+log[salt][ base ]pOH = pK _{ b }+\log \frac{[ \text{salt} ]}{[\text { base }]} At half stage of titration [[ salt ]=[]=[ base ]] as pOH=pKb=4.74 pOH = pK _{ b }=4.74 pH=14pOH=144.74=9.26pH =14- pOH =14-4.74=9.26