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Question

Chemistry Question on sulphur

4.6kJ4.6 \,kJ heat is liberated on burning 0.5g0.5 \,g of sulphur. The enthalpy of formation of SO2SO_{2} is: [molecular weight of S=32,O=16]S = 32, O = 16]

A

#ERROR!

B

- 294.4 kJ

C

#ERROR!

D

- 462.4 kJ

Answer

- 294.4 kJ

Explanation

Solution

Sulphur burns in oxygen according to the following equation S32g+O2SO2+ΔHf\underset{32 g}{ S }+ O _{2} \longrightarrow SO _{2}+\Delta H_{f} 0.5g0.5\, g S liberate =4.6kJ=4.6 \,kJ heat 1gS1\, g \,S liberate =4.60.5kJ=\frac{4.6}{0.5} kJ 32gS32\, g \,S will liberate =4.60.5×32=\frac{4.6}{0.5} \times 32 =294.4kJ=294.4 \,kJ Heat of formation is the amount of heat liberated or absorbed when one mole of compound is formed from its constituent elements hence, Heat of formation of SO2=294.4kJSO _{2}=-294.4\, kJ