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Question

Chemistry Question on Equilibrium

4.5moles4.5 \,moles each of hydrogen and iodine were heated in a sealed ten litre vessel. At equilibrium 3 moles of HI were found. The equilibrium constant for H2(g)+I2(g) {H_{2(g)} +I_{2(g)}} is

A

11

B

1010

C

55

D

0.330.33

Answer

11

Explanation

Solution

2moles2\, moles of HIHI are formed from 1mole1\, mole of H2H_2 and I2I_2. H2+I2?2HI Initialmoles4.54.50 Atequilibrium4.51.54.51.53 =3=3\begin{matrix}\therefore&H_{2}&+&I_{2}&?&2HI\\\ Initial\, moles&4.5&&4.5&&0\\\ At \,equilibrium&4.5-1.5&&4.5-1.5&&3\\\ &=3&&=3&&\end{matrix} K=[Hi]2[H2][I2]=(3)23×3=1K=\frac{\left[Hi\right]^{2}}{\left[H_{2}\right]\left[I_{2}\right]}=\frac{\left(3\right)^{2}}{3\times3}=1