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Question

Chemistry Question on Thermodynamics

4.48 litres of an ideal gas at STP requires 12.0 calories to raise its temperature by 15\circC at constant volume. The CpC_p of the gas is

A

3 cal

B

4 cal

C

7 cal

D

6 cal

Answer

6 cal

Explanation

Solution

No. of moles in 4-484 of ideal gas at STP = 4.4822.4\frac{4.48}{22.4} = 0.2 Thus to raise the temperature of 0-2 mol of the ideal gas, through 15\circC heat absorbed = 12 cal. \therefore To raise the temperature of 1 mol of the gas through 1\circC, heat absorbed = \frac{12}{15} \times \frac{1}{0.2 = 4 cal i.e., Cv = 4 cal CP = Cv + R = 4 + 2 cal = 6 cal