Question
Chemistry Question on Thermodynamics
4.48 litres of an ideal gas at STP requires 12.0 calories to raise its temperature by 15∘C at constant volume. The Cp of the gas is
A
3 cal
B
4 cal
C
7 cal
D
6 cal
Answer
6 cal
Explanation
Solution
No. of moles in 4-484 of ideal gas at STP = 22.44.48 = 0.2 Thus to raise the temperature of 0-2 mol of the ideal gas, through 15∘C heat absorbed = 12 cal. ∴ To raise the temperature of 1 mol of the gas through 1∘C, heat absorbed = \frac{12}{15} \times \frac{1}{0.2 = 4 cal i.e., Cv = 4 cal CP = Cv + R = 4 + 2 cal = 6 cal