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Question

Question: In the reaction sequence, the product (B) is:...

In the reaction sequence,

the product (B) is:

Answer

Cyclohexane

Explanation

Solution

Cyclohexanone undergoes reaction with ethanethiol (HSCH2CH3HSCH_2CH_3) in the presence of an acid catalyst (H+H^+) to form the corresponding dithioacetal (A). This dithioacetal is then reduced by hydrogen gas in the presence of a nickel catalyst (Raney nickel) and heat. This process, known as desulfurization, cleaves the C-S bonds and replaces them with C-H bonds, converting the dithioacetal functional group (C(SR)2C(SR)_2) into a methylene group (CH2CH_2). Therefore, the carbonyl group of cyclohexanone is effectively reduced to a methylene group, yielding cyclohexane as the final product (B).