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Question

Chemistry Question on Thermodynamics

28.0L28.0\, L of CO2CO _2 is produced on complete combustion of 168L168 \, L gaseous mixture of ethene and methane at 25C25^{\circ} C and 1atm1 \, atm Heat evolved during the combustion process is ______kJkJ Given : ΔHc(CH4)=900kJmol1\Delta H _{ c }\left( CH _4\right)=-900 \, kJ\, mol ^{-1} ΔHc(C2H4)=1400kJmol1\Delta H _{ c }\left( C _2 H _4\right)=-1400\, kJ \, mol ^{-1}

Answer

The correct answer is 925.

⇒28=16.8+x
x=11.2L
nCH4​​=RTPV​=0.082×2981×5.6​=0.229 mole
nC2​H2​​=0.082×29811.2​=0.458 mole
∴ Heat evolved =0.229×900+0.458×1400
=206.1+641.2
=847.3kJ