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Question

Question: Which among the following compounds has lowest acidic strength?...

Which among the following compounds has lowest acidic strength?

A

Ethyl alcohol

B

t-Butyl alcohol

C

Phenol

D

p-nitrophenol

Answer

t-Butyl alcohol

Explanation

Solution

The acidic strength is inversely proportional to the pKa value. A higher pKa indicates a lower acidic strength.

  • Ethyl alcohol: pKa ≈ 16
  • t-Butyl alcohol: pKa ≈ 19
  • Phenol: pKa ≈ 10
  • p-Nitrophenol: pKa ≈ 7

Since t-Butyl alcohol has the highest pKa (~19), it is the least acidic.