Question
Question: \(20mL\) of \(0.1N\) \(HCl\) is mixed with \(20mL\) of\(0.1N\) \(KOH\). The \(pH\) of the solution w...
20mL of 0.1N HCl is mixed with 20mL of0.1N KOH. The pH of the solution would be:
A: 0
B: 7
C: 2
D: 9
Solution
pH is the measure of H+ions released by a substance when dissolved in water. On the basis of pH it is defined whether the substance is acidic or basic. Species having pH from 0 to 7are acidic and substances having pH from 7 to 14 are basic in nature.
Formula used: pH=−log[H+]
Where [H+] is concentration of H+ ions, which will be given by the following formula.
[H+]=N×V Or [OH−]=N×V
Where N is normality and V is volume
Complete answer:
In case of HCl [H+]=0.1×20ml=2mM
In case of KOH [OH−]=0.1×20ml=2mM
As seen there are no extra [H+] ions in the solution as they are completely neutralized by equal concentration of [OH−] coming from KOH. So our resulting solution will be neutral and we know neutral solution is having pH=7
Therefore our answer to this question will be option B that is 7 .
Additional information:
The concentration of a solution is also called molarity. Molarity is the measure of the number of moles present per liter of solution. It can be calculated as:
Molarity =M×Vm×1000 where mis given mass of substance, M is molar mass of substance and V is volume of solution. Units of molarity aremolL−1 .
Normality (N) is also known as the equivalent concentration of a solution. Normality is a measure of gram equivalent weight per liter of solution. The equivalent weight of an element is its gram atomic weight divided by its valence. Gram atomic weight is also known as atomic mass. The normality of a solution can be calculated as:
Normality=E×Vm Wherem weight of solute in grams, E is equivalent weight of substance and V is volume of solution in liter.
Note:
pHof any solution is the degree to measure whether the solution is acidic, basic or neutral.
For acidic solution 0<pH<7
For neutral solution pH=7
For basic solution 7<pH<14