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Question: 20 mL of a sample of \({\operatorname{H} _2}{O_2}\) gives 400 mL oxygen measured at \[NTP\]. The sam...

20 mL of a sample of H2O2{\operatorname{H} _2}{O_2} gives 400 mL oxygen measured at NTPNTP. The sample should be labelled as-
A) 5V H2O2{\text{5V}}{\text{ }}{{\text{H}}_{\text{2}}}{{\text{O}}_{\text{2}}}
B) dil. H2O2{\text{dil}}{\text{. }}{{\text{H}}_{\text{2}}}{{\text{O}}_{\text{2}}}
C) anhy. H2O2{\text{anhy}}{\text{. }}{{\text{H}}_{\text{2}}}{{\text{O}}_{\text{2}}}
D) 20V H2O2{\text{20V }}{{\text{H}}_{\text{2}}}{{\text{O}}_{\text{2}}}

Explanation

Solution

NTP means Normal temperature and pressure, which states that at NTP we can measure the value of volume, mass, pressure, etc. and we get a perfect result, so NTP is Used.
Here given the volume of H2O2{\operatorname{H} _2}{O_2} and O2{\operatorname{O} _2}, so the answer may be written in volume. So we have to take a look at option A and option D.

Complete step by step answer:
Here 20 mL of a sample of H2O2{\operatorname{H} _2}{O_2} gives 400 mL of oxygen in NTP.
So for labelling, we have to find that 1 mL of H2O2{\operatorname{H} _2}{O_2} can give how much volume of oxygen.
So,
20 mL of the sample H2O2{\operatorname{H} _2}{O_2} gives 400 mL O2{\operatorname{O} _2}
1 mL of the sample H2O2{\operatorname{H} _2}{O_2} gives \dfrac{{{\text{400}}}}{{{\text{20}}}}{\text{ = 20;mL }}{{\text{O}}_{\text{2}}}
i.e. The sample should be labelled as 20V  H2O220{\text{V}}\;{H_2}{O_2}

So the option (D) is correct.

Note: Here we have found the volume percentage sometimes there would be another representation like mole, molar concentration etc.
Then for those cases, we have to solve by calculating mole and molar mass or atomic mass.