Question
Question: A spherical inextensible balloon filled with hydrogen is at rest in air (Molar mass 30 gm/mol). The ...
A spherical inextensible balloon filled with hydrogen is at rest in air (Molar mass 30 gm/mol). The volume of balloon is V = 1m³. The temperature (300 K) and pressure (100kPa) of hydrogen can be assumed to be the same as that of the surrounding air. Assume the temperature to be constant. (A) Mass of the balloon without hydrogen is nearly 1.12 kg (B) Assuming barometric formula, the balloon is in stable equilibrium for displacement in vertical direction. (C) Assuming barometric formula, the balloon is in unstable equilibrium for displacement in vertical direction. (D) The buoyant force is 15 times the weight of hydrogen filled in the balloon (in magnitude)

Mass of the balloon without hydrogen is nearly 1.12 kg
Assuming barometric formula, the balloon is in stable equilibrium for displacement in vertical direction.
Assuming barometric formula, the balloon is in unstable equilibrium for displacement in vertical direction.
The buoyant force is 15 times the weight of hydrogen filled in the balloon (in magnitude)
A, B, D
Solution
The number of moles of hydrogen is calculated using the ideal gas law: n=RTPV=(8.314 J/(mol\cdotpK))(300 K)(100×103 Pa)(1 m3)≈40.09 mol. The mass of hydrogen is mH2=n×MH2=40.09 mol×0.002 kg/mol≈0.0802 kg. The mass of displaced air is mair=n×Mair=40.09 mol×0.03 kg/mol≈1.203 kg. The mass of the balloon is mballoon=mair−mH2=1.203 kg−0.0802 kg≈1.123 kg. (Option A is correct). The buoyant force is FB=mairg and the weight of hydrogen is WH2=mH2g. The ratio WH2FB=mH2mair≈0.08021.203≈15.0. (Option D is correct). For vertical equilibrium, the buoyant force FB(h)=ρair(h)Vg. The atmospheric density decreases with height (ρair(h)=ρ0e−Mairgh/RT). A small upward displacement increases height, decreasing density and thus buoyant force, resulting in a downward restoring force. A small downward displacement decreases height, increasing density and buoyant force, resulting in an upward restoring force. This indicates stable equilibrium. (Option B is correct, C is incorrect).
