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Question

Chemistry Question on Redox reactions

2MnO4+bI+cH2OxI2+yMnO2+zOH2 \text{MnO}_4^{-} + b \text{I}^{-} + c \text{H}_2\text{O} \rightarrow x \text{I}_2 + y \text{MnO}_2 + z \text{OH}^{-}
If the above equation is balanced with integer coefficients, the value of zz is \\_\\_\\_\\_\\_\\_.

Answer

Reduction Half Reaction:

2MnO42MnO22\text{MnO}_4^- \rightarrow 2\text{MnO}_2 2MnO4+4H2O+6e2MnO2+8OH2\text{MnO}_4^- + 4\text{H}_2\text{O} + 6e^- \rightarrow 2\text{MnO}_2 + 8\text{OH}^-

Oxidation Half Reaction:

2II2+2e2\text{I}^- \rightarrow \text{I}_2 + 2e^- 6I3I2+6e6\text{I}^- \rightarrow 3\text{I}_2 + 6e^-

Adding the oxidation half and reduction half, we get the net reaction as:

2MnO4+6I+4H2O3I2+2MnO2+8OH2\text{MnO}_4^- + 6\text{I}^- + 4\text{H}_2\text{O} \rightarrow 3\text{I}_2 + 2\text{MnO}_2 + 8\text{OH}^-

Thus, z=8z = 8.