Solveeit Logo

Question

Question: In constant volume, container of 0.82 litre, log P vs log T is plotted as shown in graph. Calc numbe...

In constant volume, container of 0.82 litre, log P vs log T is plotted as shown in graph. Calc number of moles of ideal gas present in container:

Answer

100

Explanation

Solution

The ideal gas law is PV=nRTPV = nRT. Since the volume (V) is constant, we can rearrange the equation to P=nRVTP = \frac{nR}{V}T. Taking the logarithm of both sides, we get logP=log(nRV)+logT\log P = \log(\frac{nR}{V}) + \log T. This equation is in the form of a straight line y=mx+cy = mx + c, where y=logPy = \log P, x=logTx = \log T, the slope m=1m=1, and the y-intercept c=log(nRV)c = \log(\frac{nR}{V}). From the graph, the y-intercept is given as 1. Therefore, log(nRV)=1\log(\frac{nR}{V}) = 1, which implies nRV=101=10\frac{nR}{V} = 10^1 = 10. Given V=0.82V = 0.82 litre and using the ideal gas constant R=0.0821R = 0.0821 L atm/(mol K), we can solve for the number of moles (n): n=10×VR=10×0.82 L0.0821 L atm / (mol K)=8.20.0821 mol=100 moln = \frac{10 \times V}{R} = \frac{10 \times 0.82 \text{ L}}{0.0821 \text{ L atm / (mol K)}} = \frac{8.2}{0.0821} \text{ mol} = 100 \text{ mol}.