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Question: 1/2 mole of helium is contained in a container at STP. How much heat energy is needed to double the ...

1/2 mole of helium is contained in a container at STP. How much heat energy is needed to double the pressure of the gas, (volume is constant) heat capacity of gas is 3 J g–1 K–1.

A

1436 J

B

736 J

C

1638 J

D

5698 J

Answer

1638 J

Explanation

Solution

Here, n=12,cv=3Jg1K1,M=4n = \frac{1}{2},c_{v} = 3Jg^{- 1}K^{- 1},M = 4

CV=Mcv=4×3=12mol1K1\therefore C_{V} = Mc_{v} = 4 \times 3 = 12mol^{- 1}K^{- 1}

At constant volumePT.P \propto T.

P2P1=T2T1=2,T2=2T1\therefore\frac{P_{2}}{P_{1}} = \frac{T_{2}}{T_{1}} = 2,T_{2} = 2T_{1}

Rise in temperature ΔT=T2T1\Delta T = T_{2} - T_{1}

=2T1T1=T1=273K= 2T_{1} - T_{1} = T_{1} = 273K

Heat required, ΔQ=nCVΔT\Delta Q = nC_{V}\Delta T

=12×12×273=1638J= \frac{1}{2} \times 12 \times 273 = 1638J