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Question: $10mL C_4H_x(g)$ requires $55mL O_2(g)$ for its complete combustion. Find the value of $x$....

10mLC4Hx(g)10mL C_4H_x(g) requires 55mLO2(g)55mL O_2(g) for its complete combustion. Find the value of xx.

A

4

B

6

C

8

D

10

Answer

The value of xx is 6.

Explanation

Solution

The complete combustion of a hydrocarbon CaHbC_aH_b is represented by the balanced chemical equation:

CaHb(g)+(a+b4)O2(g)aCO2(g)+b2H2OC_aH_b(g) + (a + \frac{b}{4}) O_2(g) \rightarrow a CO_2(g) + \frac{b}{2} H_2O

In this problem, the hydrocarbon is C4HxC_4H_x. So, the balanced chemical equation for the combustion of C4HxC_4H_x is:

C4Hx(g)+(4+x4)O2(g)4CO2(g)+x2H2OC_4H_x(g) + (4 + \frac{x}{4}) O_2(g) \rightarrow 4 CO_2(g) + \frac{x}{2} H_2O

According to Gay-Lussac's Law of Gaseous Volumes, when gases react at the same temperature and pressure, the ratio of their volumes is equal to the ratio of their stoichiometric coefficients in the balanced chemical equation.

From the balanced equation, 1 volume of C4Hx(g)C_4H_x(g) reacts with (4+x4)(4 + \frac{x}{4}) volumes of O2(g)O_2(g).

We are given that 10mL10mL of C4Hx(g)C_4H_x(g) requires 55mL55mL of O2(g)O_2(g) for complete combustion. Using the ratio of volumes:

Volume of C4HxVolume of O2=Stoichiometric coefficient of C4HxStoichiometric coefficient of O2\frac{\text{Volume of } C_4H_x}{\text{Volume of } O_2} = \frac{\text{Stoichiometric coefficient of } C_4H_x}{\text{Stoichiometric coefficient of } O_2}

10 mL55 mL=1(4+x4)\frac{10 \text{ mL}}{55 \text{ mL}} = \frac{1}{(4 + \frac{x}{4})}

Simplify the fraction on the left side:

1055=211\frac{10}{55} = \frac{2}{11}

So, the equation becomes:

211=14+x4\frac{2}{11} = \frac{1}{4 + \frac{x}{4}}

Cross-multiply:

2×(4+x4)=11×12 \times (4 + \frac{x}{4}) = 11 \times 1

8+2x4=118 + \frac{2x}{4} = 11

8+x2=118 + \frac{x}{2} = 11

Subtract 8 from both sides:

x2=118\frac{x}{2} = 11 - 8

x2=3\frac{x}{2} = 3

Multiply by 2:

x=3×2x = 3 \times 2

x=6x = 6

Thus, the value of xx is 6.