Question
Question: 100ml of \[0.1M\] \[HCl\] is mixed with \(100ml\) of \[0.01M\]\[HCl\] .The \[pH\] of the resulting s...
100ml of 0.1M HCl is mixed with 100ml of 0.01M$$$$HCl .The pH of the resulting solution is:
A. 2.0
B. 1.0
C. 1.26
D. None of these
Solution
The term “pH” is an abbreviation for the “potential of hydrogen.” pH is a unit of measurement which represents the concentration of hydrogen ions in a solution.
Complete step by step answer:
To calculate the pH of an aqueous solution you need to know the concentration of the hydronium ion in moles per liter (molarity). The pH is then calculated using the expression:
pH=−log[H3O]+
Calculating the Hydronium Ion Concentration from pH
The hydronium ion concentration can be found from the pH by the reverse of the mathematical operation employed to find the pH .
[H3O]+=10−pH
Or
[H3O]+=antilog(−pH)
Calculating pOH
To calculate the pOH of a solution you need to know the concentration of the hydroxide ion in moles per liter (molarity). The pOH is then calculated using the expression:
pOH=−log[OH]−
Calculating the Hydroxide Ion Concentration from pOH
The hydroxide ion concentration can be found from the pOH by the reverse mathematical operation employed to find the pOH .
[OH]−=10−pOH
Or
[OH]−=antilog(−pOH)
Relationship Between and pOH .
The pH and pOH of a water solution at 25∘C are related by the following equation.
pH+pOH=14
Step by step solution: When you add two different concentrations of the same strong acid, the pH contribution will be from both concentrations.
M1=0.1M V1=100ml M2=0.01M V2=100ml
Final volume of solution is 100+100=200ml
The final concentration of mixture will be calculated as
MV=M1V1+M2V2
= M(100+100)=0.1×100+0.01×100M
M=200(10+1)=0.055M
pH=−log[H+]
=−log(0.055)
=1.259∼1.26
So, the correct answer is Option C.
Note: The pH scale describes the acidity of the solution: acidic, neutral, or basic A solution with a pH less than 7 is an acid, exactly 7 is a neutral solution, and above 7 is a base. Bases have less hydrogen ions but more hydroxide ions, represented by the pOH or “potential of hydroxide ions.”
Acidic | Neutral | Basic |
---|---|---|
Less than 7 | 7 | Greater than 7 |