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Question

Chemistry Question on Hydrocarbons

100mL100\, mL of 0.1M0.1\, M acetic acid is completely neutralized using a standard solution of NaOHNaOH.The volume of Ethane obtained at STPSTP after the complete electrolysis of the resulting solution is

A

112 mL

B

56 mL

C

224 mL

D

560 mL

Answer

112 mL

Explanation

Solution

Acetic acid on electrolysis gives ethane as

Given moles of acetic acid,

CH3COOH=0.1×1001000=0.01CH _{3} COOH =\frac{0.1 \times 100}{1000}=0.01
2molCH3COOH\because 2\, mol CH _{3} COOH gives C2H6=22.4LC _{2} H _{6}=22.4\, L
0.01molCH3COOH\therefore 0.01 \,mol CH _{3} COOH will give

C2H6=22.4×0.012C _{2} H _{6}=\frac{22.4 \times 0.01}{2}
=0.112L=0.112\, L
=112mL=112\, mL