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Question: 10 mL of H<sub>2</sub>O<sub>2</sub> solution on treatment with KI and titration of liberated I<sub>2...

10 mL of H2O2 solution on treatment with KI and titration of liberated I2, required 10 mL of 1N hypo. Thus H2O2 is –

A

1 N

B

5.6 volume

C

17 g L–1

D

All are correct

Answer

All are correct

Explanation

Solution

H2O2 + 2I ® I2

I2 + 2S2O32{}_{3}^{2–}® S4O62{}_{6}^{2–}+ 2I

H2O2 º I2 º 2S2O32{}_{3}^{2–}

N1V1 = N2V2

H2O2 hypo

N1(H2O2) = 10×110\frac{10 \times 1}{10}= 1N

Conc. = N × E = 17 g/litre

Volume strength = 5.6 × normality

= 5.6 × 1

= 5.6 volume